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作为场效应晶体管活性成分的π-扩展四硫富瓦烯衍生物的结构与电子特性

Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors.

作者信息

Campos Antonio, Oxtoby Neil, Galindo Sergi, Pfattner Raphael, Veciana Jaume, Bromley Stefan T, Rovira Concepció, Mas-Torrent Marta

机构信息

Institut de Ciència de Materials de Barcelona (ICMAB-CSIC) , and Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN) , Campus Universitari de Bellaterra , Cerdanyola , E-08193 Barcelona , Spain . Email:

Departament de Ciència de Materials i Física Química & Institut de Química Teòrica i Computacional (IQTCUB) , Universitat de Barcelona , E-08028 Barcelona , Spain ; Institució Catalana de Recerca i Estudis Avançats (ICREA) , E-08010 Barcelona , Spain.

出版信息

CrystEngComm. 2016 Sep 7;18(33):6149-6152. doi: 10.1039/c6ce01200k. Epub 2016 Jul 12.

DOI:10.1039/c6ce01200k
PMID:27774040
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5059789/
Abstract

The electronic and structural properties of two tetrathiafulvalene derivatives bearing aromatic benzene rings are reported. Thin film transistors of these materials show p-type characteristics with comparable mobility values. It is found that the rigidification of the molecule is beneficial for reducing the reorganisation energy but also has an unfavorable impact on the electronic structure dimensionality.

摘要

报道了两种带有芳香苯环的四硫富瓦烯衍生物的电子和结构性质。这些材料的薄膜晶体管表现出具有可比迁移率值的p型特性。发现分子的刚性化有利于降低重组能，但对电子结构维度也有不利影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/e7ba3da42a6a/c6ce01200k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/3077acd49aa6/c6ce01200k-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/34c7e43b5257/c6ce01200k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/47f72dd138fe/c6ce01200k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/53c843656e90/c6ce01200k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/e7ba3da42a6a/c6ce01200k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/3077acd49aa6/c6ce01200k-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/34c7e43b5257/c6ce01200k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/47f72dd138fe/c6ce01200k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/53c843656e90/c6ce01200k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bc41/5059789/e7ba3da42a6a/c6ce01200k-f4.jpg

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