可见光介导的烯酰胺自由基二氟甲基化反应用于含CFH杂环的合成。
Visible-light-mediated radical oxydifluoromethylation of olefinic amides for the synthesis of CFH-containing heterocycles.
作者信息
Fu Weijun, Han Xin, Zhu Mei, Xu Chen, Wang Zhiqiang, Ji Baoming, Hao Xin-Qi, Song Mao-Ping
机构信息
College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, Henan 471022, China.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan 450052, China.
出版信息
Chem Commun (Camb). 2016 Nov 8;52(91):13413-13416. doi: 10.1039/c6cc07771d.
The visible-light-mediated oxydifluoromethylation of olefinic amides with difluoromethyl sulfones has been explored. This method allows for an efficient and practical synthesis of a variety of CFH-containing benzoxazines and oxazolines bearing various functional groups under mild conditions.
已对可见光介导的烯酰胺与二氟甲基砜的氧二氟甲基化反应进行了探索。该方法能够在温和条件下高效且实用地合成多种含有CFH的、带有各种官能团的苯并恶嗪和恶唑啉。
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