Yokokita Takuya, Kasamatsu Yoshitaka, Kino Aiko, Haba Hiromitsu, Shigekawa Yudai, Yasuda Yuki, Nakamura Kouhei, Toyomura Keigo, Komori Yukiko, Murakami Masashi, Yoshimura Takashi, Takahashi Naruto, Morita Kosuke, Shinohara Atsushi
Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
Nishina Center for Accelerator-Based Science, RIKEN, Wako, Saitama 351-0198, Japan.
Dalton Trans. 2016 Nov 29;45(47):18827-18831. doi: 10.1039/c6dt03497g.
We successfully observed the equilibrium state of the chemical reactions for superheavy elements on a one-atom-at-a-time scale; we investigated the time dependence of the extraction behaviour of element 104, Rf. The distribution coefficient of Rf in 9 M HCl was found to be higher than those of its homologous elements, probably due to differences in the chloride complexation of Rf.
我们成功地在一次一个原子的尺度上观测到了超重元素化学反应的平衡状态；我们研究了104号元素钅卢（Rf）萃取行为的时间依赖性。发现Rf在9M盐酸中的分配系数高于其同族元素，这可能是由于Rf的氯络合作用存在差异。
