Department of Chemistry, Imperial College London, South Kensington, London, SW7 2AZ, UK.
Angew Chem Int Ed Engl. 2016 Dec 23;55(52):16031-16034. doi: 10.1002/anie.201608599. Epub 2016 Nov 23.
Through a dramatic advance in the coordination chemistry of the zinc-hydride bond, we describe the trajectory for the approach of this bond to transition metals. The dynamic reaction coordinate was interrogated through analysis of a series of solid state structures and is one in which the TM-H-Zn angle becomes increasingly acute as the TM-Zn distance decreases. Parallels may be drawn with the oxidative addition of boron-hydrogen and silicon-hydrogen bonds to transition metal centers.
通过锌-氢键配位化学的显著进展，我们描述了该键向过渡金属接近的轨迹。通过对一系列固态结构的分析，研究了动态反应坐标，其中 TM-H-Zn 角随着 TM-Zn 距离的减小而变得越来越锐。可以与硼-氢键和硅-氢键向过渡金属中心的氧化加成进行类比。
