Butler Michael J, Crimmin Mark R
Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ, UK.
Chem Commun (Camb). 2017 Jan 24;53(8):1348-1365. doi: 10.1039/c6cc05702k.
The preparation and applications of heterobimetallic complexes continue to occupy researchers in the fields of organometallic, main group, and coordination chemistry. This interest stems from the promise these complexes hold as precursors to materials, reagents in synthesis and as new catalysis. Here we survey and organise the state-of-the-art understanding of the TM-H-M linkage (M = Mg, Zn, Al, Ga). We discuss the structure and bonding in these complexes, their known reactivity, and their largely unrealised potential in catalysis.
异双金属配合物的制备及其应用一直吸引着有机金属化学、主族化学和配位化学领域的研究人员。这种兴趣源于这些配合物作为材料前体、合成试剂和新型催化剂的潜力。在此，我们综述并梳理了目前对TM-H-M键（M = Mg、Zn、Al、Ga）的前沿认识。我们讨论了这些配合物的结构和键合、已知的反应活性以及它们在催化方面尚未充分实现的潜力。
