Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Golone-Nankai Joint Laboratory for New Materials Computational Centre for Molecular Science, Institute of New Energy Material Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, 300350, China.
Adv Mater. 2017 Feb;29(6). doi: 10.1002/adma.201604108. Epub 2016 Nov 25.
2D composites with S doping into N-rich carbon nanosheets are fabricated, whose interlayer distance becomes large enough for Na insertion and diffusion. The large surface area and stable structure also provide more sites for Na adsorption, leading to high Na-storage capacity and excellent rate performance. Moreover, Faradaic reactions between Na and tightly bound S is beneficial for further improvement of Na-storage capacity.
2D 复合材料具有 S 掺杂的富 N 碳纳米片,其层间距变得足够大,可用于 Na 的插入和扩散。大的表面积和稳定的结构也为 Na 吸附提供了更多的位点,从而实现了高的储钠容量和优异的倍率性能。此外,Na 与紧密结合的 S 之间的法拉第反应有利于进一步提高储钠容量。