Department of Earth Science and Engineering, Imperial College London , London SW7 2AZ, United Kingdom.
The Boeing Company , 5301 Bolsa Ave., Huntington Beach, CA 92647, United States.
Chem Rev. 2016 Nov 23;116(22):13633-13684. doi: 10.1021/acs.chemrev.6b00284. Epub 2016 Nov 9.
Solid oxide fuel cells (SOFCs) are a rapidly emerging energy technology for a low carbon world, providing high efficiency, potential to use carbonaceous fuels, and compatibility with carbon capture and storage. However, current state-of-the-art materials have low tolerance to sulfur, a common contaminant of many fuels, and are vulnerable to deactivation due to carbon deposition when using carbon-containing compounds. In this review, we first study the theoretical basis behind carbon and sulfur poisoning, before examining the strategies toward carbon and sulfur tolerance used so far in the SOFC literature. We then study the more extensive relevant heterogeneous catalysis literature for strategies and materials which could be incorporated into carbon and sulfur tolerant fuel cells.
固体氧化物燃料电池（SOFC）是一种在低碳世界中迅速崛起的能源技术，具有高效率、潜在的使用含碳燃料的能力以及与碳捕获和储存的兼容性。然而，目前最先进的材料对硫的容忍度较低，硫是许多燃料中的常见污染物，而且在使用含碳化合物时，由于碳沉积，它们容易失活。在这篇综述中，我们首先研究了碳和硫中毒背后的理论基础，然后检查了迄今为止 SOFC 文献中用于提高碳和硫耐受性的策略。然后，我们研究了更广泛的相关多相催化文献，以寻找可纳入碳和硫耐受燃料电池的策略和材料。
