Hendrickson Kenville E, Ma Lin, Cohn Gil, Lu Yingying, Archer Lynden A
School of Chemical and Biomolecular Engineering Cornell University 120 Olin Hall Ithaca NY 14853 USA.
Department of Materials Science and Engineering Cornell University Ithaca NY 14853 USA.
Adv Sci (Weinh). 2015 Apr 15;2(5):1500068. doi: 10.1002/advs.201500068. eCollection 2015 May.
is limited in part by the dissolution of lithium-polysulfide in the electrolyte. Remarkably, it is found that removal of the conventional membrane separator in a Li-S cell improves sulfur utilization and cycling performance, whether the sulfur is initially contained in the cathode or electrolyte. An optimized cell design yields discharge capacities as high as 980 mA h g after 100 cycles.
部分受限于锂多硫化物在电解质中的溶解。值得注意的是,研究发现,在锂硫电池中去除传统的隔膜会提高硫的利用率和循环性能,无论硫最初是包含在阴极还是电解质中。经过优化的电池设计在100次循环后可产生高达980 mA h g的放电容量。