Department of Food Technology, Faculty of Science, Chulalongkorn University Bangkok, 10330, Thailand.
Department of Food Technology, Faculty of Science, Chulalongkorn University Bangkok, 10330, Thailand.
Carbohydr Polym. 2017 Feb 10;157:748-756. doi: 10.1016/j.carbpol.2016.09.007. Epub 2016 Oct 13.
This research determined the effects of starch concentration (3.5-5.0%w/w), and plasticizer [glycerol (0-30%w/w) or sorbitol (0-60%w/w)] on properties of mung bean starch (MBS) films. The result showed that increasing plasticizer concentration tended to decrease tensile strength (TS), elastic modulus (EM) and oxygen permeability (OP); but increase elongation (%E), solubility, water vapor permeability (WVP) and seal strength. The extent of those changes also depended on starch concentration. Glycerol provided better plasticizer efficiency than sorbitol. A bimodal melting endotherm of retrograded structure was evident in non-plasticized film. However, only a low temperature endotherm was observed in polyol-plasticized films, indicating a plasticizer-induced structural modification. The developed ductile MBS films, (TS of 7.14±0.95 to 46.30±3.09MPa, %E of 2.46±0.21 to 56.95±4.34% and EM of 16.29±3.40 to 1428.45±148.72MPa) with an OP of 0.2397±0.0365 to 1.1520±0.1782 ccmm/mdaykPa and seal strength up to 422.36±7.93N/m, demonstrated in this study indicate the potential for food packaging applications.
本研究确定了淀粉浓度(3.5-5.0%w/w)和增塑剂[甘油(0-30%w/w)或山梨糖醇(0-60%w/w)]对绿豆淀粉(MBS)膜性能的影响。结果表明,增塑剂浓度的增加往往会降低拉伸强度(TS)、弹性模量(EM)和氧气透过率(OP);但增加伸长率(%E)、溶解度、水蒸气透过率(WVP)和密封强度。这些变化的程度也取决于淀粉浓度。甘油比山梨糖醇提供更好的增塑效率。未增塑膜中存在明显的 retrograded 结构的双峰熔融吸热峰。然而,多元醇增塑膜中只观察到一个低温吸热峰,表明增塑剂诱导了结构修饰。开发出的韧性 MBS 薄膜(TS 为 7.14±0.95 至 46.30±3.09MPa,%E 为 2.46±0.21 至 56.95±4.34%和 EM 为 16.29±3.40 至 1428.45±148.72MPa),OP 为 0.2397±0.0365 至 1.1520±0.1782 ccmm/mdaykPa,密封强度高达 422.36±7.93N/m,表明其在食品包装应用方面的潜力。