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开发具有阻隔氧气和热封性能的非水溶性、韧性绿豆淀粉基可食用膜。

Development of non-water soluble, ductile mung bean starch based edible film with oxygen barrier and heat sealability.

机构信息

Department of Food Technology, Faculty of Science, Chulalongkorn University Bangkok, 10330, Thailand.

Department of Food Technology, Faculty of Science, Chulalongkorn University Bangkok, 10330, Thailand.

出版信息

Carbohydr Polym. 2017 Feb 10;157:748-756. doi: 10.1016/j.carbpol.2016.09.007. Epub 2016 Oct 13.

Abstract

This research determined the effects of starch concentration (3.5-5.0%w/w), and plasticizer [glycerol (0-30%w/w) or sorbitol (0-60%w/w)] on properties of mung bean starch (MBS) films. The result showed that increasing plasticizer concentration tended to decrease tensile strength (TS), elastic modulus (EM) and oxygen permeability (OP); but increase elongation (%E), solubility, water vapor permeability (WVP) and seal strength. The extent of those changes also depended on starch concentration. Glycerol provided better plasticizer efficiency than sorbitol. A bimodal melting endotherm of retrograded structure was evident in non-plasticized film. However, only a low temperature endotherm was observed in polyol-plasticized films, indicating a plasticizer-induced structural modification. The developed ductile MBS films, (TS of 7.14±0.95 to 46.30±3.09MPa, %E of 2.46±0.21 to 56.95±4.34% and EM of 16.29±3.40 to 1428.45±148.72MPa) with an OP of 0.2397±0.0365 to 1.1520±0.1782 ccmm/mdaykPa and seal strength up to 422.36±7.93N/m, demonstrated in this study indicate the potential for food packaging applications.

摘要

本研究确定了淀粉浓度(3.5-5.0%w/w)和增塑剂[甘油(0-30%w/w)或山梨糖醇(0-60%w/w)]对绿豆淀粉(MBS)膜性能的影响。结果表明,增塑剂浓度的增加往往会降低拉伸强度(TS)、弹性模量(EM)和氧气透过率(OP);但增加伸长率(%E)、溶解度、水蒸气透过率(WVP)和密封强度。这些变化的程度也取决于淀粉浓度。甘油比山梨糖醇提供更好的增塑效率。未增塑膜中存在明显的 retrograded 结构的双峰熔融吸热峰。然而,多元醇增塑膜中只观察到一个低温吸热峰,表明增塑剂诱导了结构修饰。开发出的韧性 MBS 薄膜(TS 为 7.14±0.95 至 46.30±3.09MPa,%E 为 2.46±0.21 至 56.95±4.34%和 EM 为 16.29±3.40 至 1428.45±148.72MPa),OP 为 0.2397±0.0365 至 1.1520±0.1782 ccmm/mdaykPa,密封强度高达 422.36±7.93N/m,表明其在食品包装应用方面的潜力。

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