高价碘（III）诱导的多米诺氧化环化反应合成环戊并[b]呋喃
Hypervalent Iodine(III)-Induced Domino Oxidative Cyclization for the Synthesis of Cyclopenta[b]furans.
作者信息
Lin Mei-Huey, Chen Yu-Chun, Chiu Shih-Hao, Chen Yun-Fan, Chuang Tsung-Hsun
机构信息
Department of Chemistry, National Changhua University of Education, Changhua 50007, Taiwan.
出版信息
Molecules. 2016 Dec 21;21(12):1713. doi: 10.3390/molecules21121713.
Abstract
A new strategy for cyclopenta[]furan synthesis mediated by hypervalent iodine(III) has been described. The approach employs diacetoxyiodobenzene-induced initial dehydrogenation to a putative trienone intermediate and triggered sequential cycloisomerization to form the cyclo-penta[]furan targets.
摘要
已经描述了一种由高价碘（III）介导的环戊并[]呋喃合成的新策略。该方法采用二乙酰氧基碘苯诱导初始脱氢生成假定的三烯酮中间体，并引发顺序环异构化以形成环戊并[]呋喃目标产物。
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