Nanoporous PdCu alloy as an excellent electrochemical sensor for HO and glucose detection.

Nanoporous (NP) PdCu alloy is easily fabricated by dealloying PdCuAl ternary alloy in dilute sulfuric acid. Selectively dissolving Al from PdCuAl alloy generates the three-dimensional uniform nanosponge architecture with narrow ligament size distribution. Benefitting from the unique nanoporous architecture and the alloying effect, the as-made NP-PdCu exhibits outstanding sensing performance towards the detection of hydrogen peroxide (HO) and glucose. Compared with NP-Pd and commercial Pd/C catalysts, the NP-PdCu alloy presents high sensitivity, wide linear range of 0.1-2.0mM, low detection limit of 2.1μM, and long-term stability toward HO detection. In addition, the NP-PdCu can efficiently detect glucose in a wide concentration range (1-30mM) with the low detection limit of 1.9μM. Moreover, the NP-PdCu exhibits good anti-interference toward ascorbic acid, uric acid, and dopamine. Characterized by easy preparation, unique electrocatalytic activity, and high structure stability, the NP-PdCu alloy possesses great application prospect to construct platform for electrochemical sensing.