Pinkowicz Dawid, Birk Francisco J, Magott Michał, Schulte Kelsey, Dunbar Kim R
Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060, Kraków, Poland.
Department of Chemistry, Texas A&M University, College Station, Texas, 77842-3012, USA.
Chemistry. 2017 Mar 13;23(15):3548-3552. doi: 10.1002/chem.201605528. Epub 2017 Feb 28.
A family of distorted trigonal pyramidal transition-metal complexes [M (N N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as candidates for mononuclear single-molecule magnets. Magnetic anisotropy of the family depends on the electronic configuration of the central ion, with the Co analogue exhibiting pronounced SMM behavior.
已对一族畸变三角锥过渡金属配合物[M (N N)Li(THF)]（M = 锰、铁、钴、镍）作为单核单分子磁体的候选物进行了研究。该族配合物的磁各向异性取决于中心离子的电子构型，其中钴类似物表现出明显的单分子磁体行为。
