Department of Chemistry, Yonsei University , 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Republic of Korea.
Chem Rev. 2017 Jul 12;117(13):8977-9015. doi: 10.1021/acs.chemrev.6b00554. Epub 2017 Jan 6.
Transition-metal-catalyzed activation of C-H and C-C bonds is a challenging area in synthetic organic chemistry. Among various methods to accomplish these processes, the approach using metal-organic cooperative catalytic systems is one of the most promising. In this protocol, organic molecules as well as transition metals act as catalysts to bring about reactions, which proceed with high efficiencies and selectivities. Various metal-organic cooperative catalytic systems developed for C-H and C-C bond activation reactions are discussed in this review. Also discussed are how each metal-organic cooperative catalyst affects the reaction mechanism and what kinds of substrates can be applied in each of the catalytic processes.
过渡金属催化的 C-H 和 C-C 键的活化是合成有机化学中的一个具有挑战性的领域。在实现这些过程的各种方法中，使用金属-有机协同催化体系的方法是最有前途的方法之一。在本方案中，有机分子以及过渡金属都可以作为催化剂来引发反应，这些反应具有高效率和选择性。本文综述了为 C-H 和 C-C 键活化反应开发的各种金属-有机协同催化体系。还讨论了每个金属-有机协同催化剂如何影响反应机理，以及在每个催化过程中可以应用哪些类型的底物。
