前列腺素和甾体烯丙基二甲基硅烷化反应的三种试剂的合成与比较：一种气相色谱法
Syntheses and comparison of three reagents for allyldimethylsilylation of prostaglandins and steroids: a gas chromatographic method.
作者信息
Steffenrud S, Borgeat P, Bertrand M J
机构信息
Inflammation and Immunology-Rheumatology, Research Unit, Le Centre Hospitalier de l'Université Laval, Quebec, Canada.
出版信息
J Chromatogr Sci. 1989 Sep;27(9):545-8. doi: 10.1093/chromsci/27.9.545.
Three reagents used for allyldimethylsilylation of prostaglandins and steroids have been prepared: N,O-bis(allyldimethylsilyl)trifluoroacetamide, N-methylallyl-dimethylsilyltrifluoroacetamide and allyldimethylsilyl-N,N-diphenylamine. The reaction kinetics of the reagents have been studied at room temperature in several solvents, and the optimal conditions for the derivatization of prostaglandins and steroids are discussed.
已制备了三种用于前列腺素和甾体烯丙基二甲基硅烷化反应的试剂
N,O-双(烯丙基二甲基硅基)三氟乙酰胺、N-甲基烯丙基二甲基硅基三氟乙酰胺和烯丙基二甲基硅基-N,N-二苯胺。在室温下于几种溶剂中研究了这些试剂的反应动力学，并讨论了前列腺素和甾体衍生化的最佳条件。
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