一种基于双功能咪唑盐/四唑盐桥的新型三维光致发光氯化亚铜聚合物。
A novel 3-D photoluminescent cuprous chloride polymer based on bifunctional imidazolate/tetrazolate bridges.
作者信息
Tang Qiuling, Zhou Jian, Almeida Paz Filipe A, Fu Lianshe, Xiao Hong, Zhou Qi, Li Ju
机构信息
College of Chemistry, Chongqing Normal University, Chongqing, 401331, P.R. China.
Department of Chemistry, University of Aveiro, CICECO-Aveiro Institute of Materials, 3810-193, Aveiro, Portugal.
出版信息
Dalton Trans. 2017 Jan 31;46(5):1372-1376. doi: 10.1039/c6dt04673h.
A novel 3-D cuprous chloride polymer [CuCl(μ-L)] (1, HL = 1-tetrazole-4-imidazole-benzene) has been hydrothermally synthesized and structurally characterized. 1 displays a 3-D network with a bimodal fsc-3,5-Cmce-2 topological type constructed by the linkages of rare [CuCl] cations and L ligands. The photoluminescence properties and density functional theory calculations of 1 have also been studied.
一种新型的三维氯化亚铜聚合物[CuCl(μ-L)]（1，HL = 1-四唑-4-咪唑-苯）已通过水热法合成并进行了结构表征。1呈现出一种三维网络结构，具有由罕见的[CuCl]阳离子和L配体连接构建的双峰fsc-3,5-Cmce-2拓扑类型。还研究了1的光致发光性质和密度泛函理论计算。
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