Tang Qiuling, Zhou Jian, Almeida Paz Filipe A, Fu Lianshe, Xiao Hong, Zhou Qi, Li Ju
College of Chemistry, Chongqing Normal University, Chongqing, 401331, P.R. China.
Department of Chemistry, University of Aveiro, CICECO-Aveiro Institute of Materials, 3810-193, Aveiro, Portugal.
Dalton Trans. 2017 Jan 31;46(5):1372-1376. doi: 10.1039/c6dt04673h.
A novel 3-D cuprous chloride polymer [CuCl(μ-L)] (1, HL = 1-tetrazole-4-imidazole-benzene) has been hydrothermally synthesized and structurally characterized. 1 displays a 3-D network with a bimodal fsc-3,5-Cmce-2 topological type constructed by the linkages of rare [CuCl] cations and L ligands. The photoluminescence properties and density functional theory calculations of 1 have also been studied.
一种新型的三维氯化亚铜聚合物[CuCl(μ-L)]（1，HL = 1-四唑-4-咪唑-苯）已通过水热法合成并进行了结构表征。1呈现出一种三维网络结构，具有由罕见的[CuCl]阳离子和L配体连接构建的双峰fsc-3,5-Cmce-2拓扑类型。还研究了1的光致发光性质和密度泛函理论计算。
