Xiao Hong, Zhou Jian, Liu Xing, Xiao Hongping, Ferreira Rute A S, Carlos Luís D, Fu Lianshe
College of Chemistry, Chongqing Normal University, Chongqing, 401331, P.R. China.
Dalton Trans. 2018 Mar 6;47(10):3253-3257. doi: 10.1039/c8dt00054a.
A novel 3-D cuprous iodide polymer [CuI(μ-L)] with a Cu/I ratio as high as 3 (1, HL = 1,3-bis(2H-tetrazol-5-yl)benzene) has been hydrothermally synthesized. The 3-D framework of 1 is constructed by the linkages of rare 1-D cationic aggregates [CuI] and anionic bi-tetrazolate bridges. 1 shows unusually thermochromic luminescent and photocatalytic properties, and its density functional theory calculation has also been studied.
一种新颖的三维碘化亚铜聚合物[CuI(μ-L)]已通过水热法合成，其铜/碘比高达3（1，HL = 1,3-双(2H-四唑-5-基)苯）。1的三维框架由罕见的一维阳离子聚集体[CuI]和阴离子双四唑桥连接而成。1表现出异常的热致变色发光和光催化性能，并且还对其进行了密度泛函理论计算研究。
