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A novel 3-D lead-iodide polymer based on the linkage of rare binuclear [PbI] cations and anionic bis(pyrazinyl)-trizole bridges.

作者信息

Liu Xing, Zhang Ting-Ting, Zhou Jian, Xiang Bin, Liu Jiang-Tao

机构信息

School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, P.R. China.

出版信息

Dalton Trans. 2021 Apr 7;50(13):4486-4489. doi: 10.1039/d1dt00471a. Epub 2021 Mar 25.

DOI:10.1039/d1dt00471a
PMID:33877167
Abstract

A novel 3-D lead-iodide polymer [PbI(μ-bpt-z)] (1, Hbpt-z = 3,5-bis(pyrazinyl)-1,2,4-trizole) has been hydrothermally prepared and structurally characterized. 1 offers the first example of a 3-D lead-iodide polymer built up from the linkage of rare binuclear [PbI] cations and anionic bis(pyrazinyl)-trizole bridges. 1 exhibits photoluminescent and photocurrent response properties, and its density functional theory calculation was also studied.

摘要

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