Carbon/two-dimensional MoTe core/shell-structured microspheres as an anode material for Na-ion batteries.

Unique-structured composite microspheres of carbon and MoTe were prepared by a two-step process. Precursor C-MoO composite microspheres were prepared by spray pyrolysis, and then the precursor was transformed into C-MoTe composite microspheres by a tellurization process. C-MoTe composites with a uniform distribution of MoTe nanocrystals (C/MoTe) and core-shell-structured C-MoTe composites (C@MoTe) were synthesized at tellurization temperatures of 450 and 600 °C, respectively. At a higher tellurization temperature of 600 °C, all of the MoTe nanocrystals moved to the surface of the microsphere because of the Ostwald ripening process. The initial discharge capacities of the C/MoTe, C@MoTe, and bare MoTe (i.e., containing no carbonaceous materials) powders for Na-ion storage at a current density of 1.0 A g were 328, 388, and 341 mA h g, respectively. The discharge capacities of the C/MoTe, C@MoTe, and bare MoTe powders for the 200 cycle were 241, 286, and 104 mA h g, respectively, and the corresponding capacity retentions, which were measured from the second cycle were 100%, 99%, and 37%, respectively. The high structural stability and well-developed two-dimensional layer of MoTe of the C@MoTe microspheres provide superior Na-ion storage properties compared to those of the C/MoTe microspheres and bare MoTe powder.