在可见光下使用铁分子催化剂将一氧化碳非敏化选择性光化学还原为一氧化碳。 （注：原文中“Non-sensitized selective photochemical reduction of CO to CO”表述有误，推测可能是“Non-sensitized selective photochemical reduction of CO₂ to CO”，若按此推测，译文为：在可见光下使用铁分子催化剂将二氧化碳非敏化选择性光化学还原为一氧化碳。）
Non-sensitized selective photochemical reduction of CO to CO under visible light with an iron molecular catalyst.
作者信息
Rao Heng, Bonin Julien, Robert Marc
机构信息
Univ Paris Diderot, Sorbonne Paris Cité, Laboratoire d'Electrochimie Moléculaire, UMR 7591 CNRS, 15 rue Jean-Antoine de Baïf, F-75205 Paris Cedex 13, France.
出版信息
Chem Commun (Camb). 2017 Mar 2;53(19):2830-2833. doi: 10.1039/c6cc09967j.
PMID:28217798
Abstract
A substituted tetraphenyl iron porphyrin, bearing positively charged trimethylammonio groups at the para position of each phenyl ring, demonstrates its ability as a homogeneous molecular catalyst to selectively reduce CO to CO under visible light irradiation in organic media without the assistance of a sensitizer and no competitive hydrogen evolution for several days.
摘要
一种取代的四苯基铁卟啉，在每个苯环的对位带有带正电荷的三甲基铵基团，在有机介质中可见光照射下，无需敏化剂辅助，能作为均相分子催化剂选择性地将CO还原为CO，并且几天内没有竞争性析氢反应。
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