Rao Heng, Bonin Julien, Robert Marc
Univ Paris Diderot, Sorbonne Paris Cité, Laboratoire d'Electrochimie Moléculaire, UMR 7591 CNRS, 15 rue Jean-Antoine de Baïf, F-75205 Paris Cedex 13, France.
Chem Commun (Camb). 2017 Mar 2;53(19):2830-2833. doi: 10.1039/c6cc09967j.
A substituted tetraphenyl iron porphyrin, bearing positively charged trimethylammonio groups at the para position of each phenyl ring, demonstrates its ability as a homogeneous molecular catalyst to selectively reduce CO to CO under visible light irradiation in organic media without the assistance of a sensitizer and no competitive hydrogen evolution for several days.
一种取代的四苯基铁卟啉，在每个苯环的对位带有带正电荷的三甲基铵基团，在有机介质中可见光照射下，无需敏化剂辅助，能作为均相分子催化剂选择性地将CO还原为CO，并且几天内没有竞争性析氢反应。
