Hirasawa T, Nagamitsu T
Shika Rikogaku Zasshi. 1977 Apr;18(42):110-7.
The plasticity, the douing time, and the working time, of the mixture of powder-liquid type methacrylic resin were measured under the various circumstances of the elapsed time and the certain temperature. Six polymethyl methacrylates, whose molecular weight was prepared by mean of gamma-ray irradiation, were used as the polymer of resin, again methyl methacrylate being used as the monomer of resin. The results obtained are as follows: (1) The plasticity is reduced with the increase of the molecular weight of the polymer. (2) The plasticity, generally, is reduced with the time elapsed, but its values appear at 10 min. and 5 min. elapsed at 16 degrees C and 23 degrees C respectively. (3) The plasticities of the mixtures of polymers with 6 X 10(4), 8 X 10(4), 20 X 10(4) and 34 X 10(4) molecular weights are increased with the increase of temperature. The plasticities of the mixtures of polymers with 60 X 10(4) and 74 X 10(4) molecular weights at 0 min. time elapsed, indicate their maximum value at 30 degrees C. At 5 min. time elapsed plasticities of all mixtures indicate their maximum value at 23 degrees C. Over 5 min. time elapsed, however, the plasticity is reduced with the increase of temperature. (4) The doughing time and the working time are reduced with the increase of molecular weight of the polymer and the temperature.
在不同的时间流逝情况和特定温度下,对粉液型甲基丙烯酸树脂混合物的可塑性、面团形成时间和工作时间进行了测量。六种通过γ射线辐照制备分子量的聚甲基丙烯酸甲酯被用作树脂的聚合物,甲基丙烯酸甲酯再次被用作树脂的单体。所得结果如下:(1)可塑性随聚合物分子量的增加而降低。(2)可塑性通常随时间流逝而降低,但其值分别在16℃和23℃下经过10分钟和5分钟时出现。(3)分子量为6×10⁴、8×10⁴、20×10⁴和34×10⁴的聚合物混合物的可塑性随温度升高而增加。分子量为60×10⁴和74×10⁴的聚合物混合物在经过0分钟时,在30℃下显示出最大值。在经过5分钟时,所有混合物的可塑性在23℃下显示出最大值。然而,经过5分钟后,可塑性随温度升高而降低。(4)面团形成时间和工作时间随聚合物分子量和温度的增加而减少。