活化C(sp) -H键与CO的光化学羧基化反应
Photochemical Carboxylation of Activated C(sp )-H Bonds with CO.
作者信息
Gui Yong-Yuan, Zhou Wen-Jun, Ye Jian-Heng, Yu Da-Gang
机构信息
Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu, 610064, PR China.
College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang, 641112, PR China.
出版信息
ChemSusChem. 2017 Apr 10;10(7):1337-1340. doi: 10.1002/cssc.201700205. Epub 2017 Mar 21.
From ugly duckling to beautiful C1: Although CO may represent an ideal C1 source, it is challenging to use it as a raw material and direct carboxylation with CO has mainly been confined to highly reactive species. However, recent significant breakthroughs have been made in photochemical carboxylation of challenging, un-acidic, C(sp )-H bonds, including benzylic, allylic and amine C-H bonds.
从丑小鸭到美丽的C1：尽管一氧化碳可能是理想的C1来源，但将其用作原料具有挑战性，并且与一氧化碳的直接羧化主要局限于高活性物种。然而，最近在具有挑战性的、非酸性的C(sp³)-H键（包括苄基、烯丙基和胺C-H键）的光化学羧化方面取得了重大突破。
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