在DMF溶剂中使用二氧化碳对有机锌试剂进行无过渡金属羧基化反应。
Transition-metal-free carboxylation of organozinc reagents using CO2 in DMF solvent.
作者信息
Kobayashi Koji, Kondo Yoshinori
机构信息
Graduate School of Pharmaceutical Sciences, Tohoku University, Aramaki-aza aoba 6-3, Aoba-ku, Sendai 980-8578, Japan.
出版信息
Org Lett. 2009 May 7;11(9):2035-7. doi: 10.1021/ol900528h.
PMID:19338291
Abstract
An efficient process for the carboxylation of functionalized organozinc reagents with CO(2) under transition-metal-free conditions was developed by employing DMF solvent in the presence of LICl.
摘要
通过在LiCl存在下使用DMF溶剂，开发了一种在无过渡金属条件下用CO₂使功能化有机锌试剂羧化的有效方法。
Zotero 插件