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一种用于乌梁素海水 - 冰 - 沉积物间汞归宿与迁移模拟的改进QWASI模型。

A modified QWASI model for fate and transport modeling of mercury between the water-ice-sediment in Lake Ulansuhai.

作者信息

Liu Yu, Li Changyou, Anderson Bruce, Zhang Sheng, Shi Xiaohong, Zhao Shengnan

机构信息

Water Conservancy and Civil Engineering College, Inner Mongolia Agricultural University, Hohhot, 010018, China.

Water Conservancy and Civil Engineering College, Inner Mongolia Agricultural University, Hohhot, 010018, China.

出版信息

Chemosphere. 2017 Jun;176:117-124. doi: 10.1016/j.chemosphere.2017.02.111. Epub 2017 Feb 23.

Abstract

Mercury contamination from industrial and agricultural drainage into lakes and rivers is a growing concern in Northern China. Lake Ulansuhai, located in Hetao irrigation district in Inner Mongolia, is the only sink for the all industrial and agricultural drainage and sole outlet for this district to the Yellow River, which is one of the main source of drinking water for the numerous cities and towns downstream. Because Ulansuahi is ice-covered during winter, the QWASI model was modified by adding an ice equation to get a more accurate understanding of the fate and transport of mercury within the lake. Both laboratory and field tests were carried out during the ice growth period. The aquivalence and mass balance approaches were used to develop the modified QWASI + ice model. The margins of error between the modelled and the measured average concentrations of Hg in ice, water, and sediment were 30%, 26.2%, and 19.8% respectively. These results suggest that the new QWASI + ice model could be used to more accurately represent the fate and transport of mercury in the seasonally ice-covered lakes, during the ice growth period.

摘要

中国北方,工农业废水排入湖泊和河流所造成的汞污染问题日益严重。位于内蒙古河套灌区的乌梁素海,是该地区工农业废水的唯一汇集地,也是该地区通向黄河的唯一出口,而黄河是下游众多城镇的主要饮用水源之一。由于乌梁素海冬季会结冰,因此对QWASI模型进行了修改,增加了一个冰方程,以便更准确地了解湖泊中汞的归宿和迁移情况。在结冰期进行了实验室测试和现场测试。采用等效性和质量平衡方法开发了改进后的QWASI + 冰模型。该模型预测的冰、水和沉积物中汞的平均浓度与实测值之间的误差范围分别为30%、26.2%和19.8%。这些结果表明,新的QWASI + 冰模型可用于更准确地描述结冰期季节性结冰湖泊中汞的归宿和迁移情况。

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