Complex Materials, Department of Materials, ETH Zürich, 8093 Zürich, Switzerland.
Nat Commun. 2017 Mar 6;8:14655. doi: 10.1038/ncomms14655.
Dense ceramic materials can form in nature under mild temperatures in water. By contrast, man-made ceramics often require sintering temperatures in excess of 1,400 °C for densification. Chemical strategies inspired by biomineralization processes have been demonstrated but remain limited to the fabrication of thin films and particles. Besides biomineralization, the formation of dense ceramic-like materials such as limestone also occurs in nature through large-scale geological processes. Inspired by the geological compaction of mineral sediments in nature, we report a room-temperature method to produce dense and strong ceramics within timescales comparable to those of conventional manufacturing processes. Using nanoscale powders and high compaction pressures, we show that such cold sintering process can be realized with water at room temperature to result in centimetre-sized bulk parts with specific strength that is comparable to, and occasionally even higher than, that of traditional structural materials like concrete.
在自然界中,致密的陶瓷材料可以在低温的水中形成。相比之下,人造陶瓷通常需要超过 1400°C 的烧结温度才能致密化。受生物矿化过程启发的化学策略已经得到证明,但仍然局限于薄膜和颗粒的制造。除了生物矿化,在自然界中,通过大规模的地质过程也会形成致密的陶瓷状材料,如石灰岩。受自然界中矿物沉积物地质压实的启发,我们报告了一种在室温下生产致密和高强度陶瓷的方法,其时间尺度与传统制造工艺相当。使用纳米级粉末和高压实,我们表明,这种冷烧结过程可以在室温下用水实现,从而得到厘米级的大块零件,其比强度可与传统结构材料(如混凝土)相媲美,甚至偶尔更高。