钇催化的分子内氢烷氧基化/克莱森重排反应序列：中到大环内酰胺的有效合成。
Yttrium-Catalyzed Intramolecular Hydroalkoxylation/Claisen Rearrangement Sequence: Efficient Synthesis of Medium-Sized Lactams.
机构信息
Collaborative Innovation Center of Chemistry for Energy Material, State Key Laboratory of Physical Chemistry of Solid Surfaces, Key Laboratory for Chemical Biology of Fujian Province and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China.
出版信息
Angew Chem Int Ed Engl. 2017 Mar 27;56(14):4015-4019. doi: 10.1002/anie.201700596. Epub 2017 Mar 7.
An efficient yttrium-catalyzed intramolecular hydroalkoxylation/Claisen rearrangement sequence has been achieved, thus enabling facile access to a diverse array of valuable medium-sized lactams. Furthermore, a mechanistic rationale for this novel cascade reaction is well supported by a variety of control experiments.
一种高效的钇催化的分子内氢烷氧基化/克莱森重排反应序列已经实现，从而能够轻松获得各种有价值的中到大环内酰胺。此外，通过各种对照实验，很好地支持了这种新型级联反应的机理。
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