吲哚的有氧光氧化条件下的交叉脱氢 C-H 胺化反应。
Cross-Dehydrogenative C-H Amination of Indoles under Aerobic Photo-oxidative Conditions.
机构信息
Gifu Pharmaceutical University 1-25-4, Daigaku-nishi, Gifu 501-1196, Japan.
出版信息
Org Lett. 2017 Mar 17;19(6):1282-1285. doi: 10.1021/acs.orglett.7b00026. Epub 2017 Mar 8.
PMID:28272890
Abstract
A novel cross-dehydrogenative C(sp)-H amination catalyzed by an organic photocatalyst is reported. The reaction is mediated by 2-tert-butylanthraquinone as a photocatalyst, harmless visible light, and aerobic oxygen as the sole oxidant without a transition-metal catalyst and or external oxidant.
摘要
本文报道了一种新型的有机光催化剂促进的交叉脱氢 C(sp)-H 胺化反应。该反应以 2-叔丁基蒽醌为光催化剂，无害可见光和有氧氧气为唯一氧化剂，无需过渡金属催化剂和/或外部氧化剂。
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