Institute of Chemistry and Chemical Engineering, Taiyuan University of Technology, 030024, PR China.
Institute of Chemistry and Chemical Engineering, Taiyuan University of Technology, 030024, PR China.
J Hazard Mater. 2017 Jun 15;332:51-58. doi: 10.1016/j.jhazmat.2017.02.052. Epub 2017 Mar 1.
Coal-oil-water slurry (COWS) synfuel can be prepared successfully by waste engine oil (WEO), water and coal in the existence of Tween 80 and SL. The effects of coal type, coal particle size distribution, and WEO blending proportion (α) on the slurryability of COWS were investigated, and certain essential properties, such as slurryability, rheology, thixotropy, and stability of COWS were examined. The results show that the maximum coal content of COWS decreases with an increment in α, ranging from 60wt.% at α=0 to 48wt.% at α=15wt.%. The apparent viscosity of COWS becomes high when the amount of WEO is increased for the same coal content. The lower heating value (19.15kJ/g) of 48wt.% COWS (α=15wt.%) is equivalent to that of CWS with 67.88wt.% coal. The mass ratio of separated supernatant to oil-water emulsion for COWS with 49wt.% coal decreases by 1.12% while the amount of WEO is increased to 15wt.% from 10wt.%. COWS exhibits the non-Newtonian pseudoplastic fluid behavior. Its pseudoplasticity and thixotropy are also promoted as the coal content of COWS is increased. And the dispersion and stabilization mechanism of COWS is discussed.
成功地以废机油(WEO)、水和煤为原料,在 Tween 80 和 SL 的存在下制备水煤浆(COWS)合成燃料。考察了煤种、煤粒径分布以及 WEO 混合比例(α)对 COWS 浆体性能的影响,并考察了 COWS 的一些基本性质,如浆体性、流变学、触变性和稳定性。结果表明,COWS 的最大煤含量随α的增加而降低,从α=0 时的 60wt.%降至α=15wt.%时的 48wt.%。当相同煤含量下增加 WEO 的量时,COWS 的表观粘度会变高。48wt.% COWS(α=15wt.%)的低热值(19.15kJ/g)与煤含量为 67.88wt.%的 CWS 相当。当 WEO 从 10wt.%增加到 15wt.%时,含 49wt.%煤的 COWS 的分离上清液与油水乳液的质量比减少了 1.12%。COWS 表现出非牛顿假塑性流体行为。随着 COWS 中煤含量的增加,其假塑性和触变性也得到了促进。并讨论了 COWS 的分散和稳定机制。