一种用于捕获大型有机分子和色谱分离的高度多孔金属有机框架。
A highly porous metal-organic framework for large organic molecule capture and chromatographic separation.
作者信息
Li Pei-Zhou, Su Jie, Liang Jie, Liu Jia, Zhang Yuanyuan, Chen Hongzhong, Zhao Yanli
机构信息
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371, Singapore.
出版信息
Chem Commun (Camb). 2017 Mar 25;53(24):3434-3437. doi: 10.1039/c7cc01063j. Epub 2017 Mar 10.
PMID:28280829
Abstract
A highly porous metal-organic framework (MOF) with large pores was successfully obtained via solvothermal assembly of a "click"-extended tricarboxylate ligand and Zn(ii) ions. The inherent feature of large-molecule accessible pores endows the MOF with a unique property for utilization toward large guest molecules.
摘要
通过“点击”扩展的三羧酸配体与锌（II）离子的溶剂热组装，成功获得了一种具有大孔的高度多孔金属有机框架（MOF）。大分子可进入孔的固有特性赋予了该MOF对大型客体分子利用的独特性能。
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