Centre for Landscape & Climate Research, University of Leicester, Geography, Leicester, LE1 7RH, UK.
The Open University, Dept. of Environment, Earth and Ecosystems, Milton Keynes, MK7 6AA, UK.
Water Res. 2017 May 15;115:229-235. doi: 10.1016/j.watres.2017.02.059. Epub 2017 Feb 27.
UV-visible spectroscopy has been shown to be a useful technique for determining dissolved organic carbon (DOC) concentrations. However, at present we are unaware of any studies in the literature that have investigated the suitability of this approach for tropical DOC water samples from any tropical peatlands, although some work has been performed in other tropical environments. We used water samples from two oil palm estates in Sarawak, Malaysia to: i) investigate the suitability of both single and two-wavelength proxies for tropical DOC determination; ii) develop a calibration dataset and set of parameters to calculate DOC concentrations indirectly; iii) provide tropical researchers with guidance on the best spectrophotometric approaches to use in future analyses of DOC. Both single and two-wavelength model approaches performed well with no one model significantly outperforming the other. The predictive ability of the models suggests that UV-visible spectroscopy is both a viable and low cost method for rapidly analyzing DOC in water samples immediately post-collection, which can be important when working at remote field sites with access to only basic laboratory facilities.
紫外-可见光谱学已被证明是一种用于测定溶解有机碳 (DOC) 浓度的有用技术。然而,目前我们在文献中没有发现任何研究调查过这种方法是否适用于来自任何热带泥炭地的热带 DOC 水样,尽管在其他热带环境中已经进行了一些工作。我们使用来自马来西亚砂拉越的两个油棕种植园的水样:i)研究单波长和双波长指标在热带 DOC 测定中的适用性;ii)建立校准数据集和一组参数,以间接计算 DOC 浓度;iii)为热带研究人员提供指导,说明在未来分析 DOC 时应使用最佳分光光度法。单波长和双波长模型方法的性能都很好,没有一种模型明显优于另一种。模型的预测能力表明,紫外-可见光谱学是一种可行的、低成本的方法,可用于在采集后立即快速分析水样中的 DOC,这在只有基本实验室设施的偏远野外站点工作时非常重要。