单体设计策略在天然产物基聚合物材料中的应用。

Monomer design strategies to create natural product-based polymer materials.

机构信息

Department of Chemistry, Department of Chemical Engineering, Department of Materials Science & Engineering, Texas A&M University, College Station, Texas 77842-3012, USA.

出版信息

Nat Prod Rep. 2017 Apr 5;34(4):433-459. doi: 10.1039/c6np00112b.

DOI:10.1039/c6np00112b

PMID:28290568

Abstract

Covering: 2010-Aug. 2016In an effort towards enhancing function and sustainability, natural products have become of interest in the field of polymer chemistry. This review details the blending of chemistries developed through synthetic organic chemistry and polymer chemistry. Through synthetic organic chemical transformations, such as functional group interconversion, a protection/deprotection series, or installation of a functional group, various designs towards novel, synthetic, bio-based polymer systems are described. This review covers several classifications of natural products - oils and fatty acids, terpenes, lignin, and sugar derivatives - focusing on exploring monomers prepared by one or more synthetic steps.

摘要

涵盖

2010 年 8 月至 2016 年

为了提高功能和可持续性，天然产物已成为聚合物化学领域的研究热点。本综述详细介绍了通过合成有机化学和聚合物化学开发的化学物质的混合。通过合成有机化学反应，如官能团转化、保护/脱保护系列或官能团的安装，可以描述各种新型、合成、生物基聚合物系统的设计。本综述涵盖了几类天然产物——油和脂肪酸、萜烯、木质素和糖衍生物——重点探讨了通过一个或多个合成步骤制备的单体。