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欧姆加热:有机合成中的一个新兴概念。

Ohmic Heating: An Emerging Concept in Organic Synthesis.

作者信息

Silva Vera L M, Santos Luis M N B F, Silva Artur M S

机构信息

Department of Chemistry & QOPNA, University of Aveiro, 3810-193, Aveiro, Portugal.

Centro de Investigação em Química (CIQUP), Departamento de Química e Bioquímica, Faculdade de Ciências da Universidade do Porto, Rua Campo Alegre 687, 4169-007, Porto, Portugal.

出版信息

Chemistry. 2017 Jun 12;23(33):7853-7865. doi: 10.1002/chem.201700307. Epub 2017 Apr 26.

Abstract

The ohmic heating also known as direct Joule heating, is an advanced thermal processing method, mainly used in the food industry to rapidly increase the temperature for either cooking or sterilization purposes. Its use in organic synthesis, in the heating of chemical reactors, is an emerging method that shows great potential, the development of which has started recently. This Concept article focuses on the use of ohmic heating as a new tool for organic synthesis. It presents the fundamentals of ohmic heating and makes a qualitative and quantitative comparison with other common heating methods. A brief description of the ohmic reactor prototype in operation is presented as well as recent examples of its use in organic synthesis at laboratory scale, thus showing the current state of the research. The advantages and limitations of this heating method, as well as its main current applications are also discussed. Finally, the prospects and potential implications of ohmic heating in future research in chemical synthesis are proposed.

摘要

欧姆加热也被称为直接焦耳加热,是一种先进的热处理方法,主要用于食品工业,以快速提高温度用于烹饪或杀菌目的。它在有机合成中用于化学反应器的加热,是一种新兴方法,显示出巨大潜力,其发展最近才开始。这篇概念文章重点关注欧姆加热作为有机合成新工具的应用。它介绍了欧姆加热的基本原理,并与其他常见加热方法进行了定性和定量比较。还介绍了运行中的欧姆反应器原型的简要描述以及其在实验室规模有机合成中的近期应用实例,从而展示了研究现状。还讨论了这种加热方法的优点和局限性及其当前的主要应用。最后,提出了欧姆加热在未来化学合成研究中的前景和潜在影响。

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