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2,2'-(2-溴-5-丁基-1,3-亚苯基)双-(1-甲基-1-苯并咪唑)氯化汞配合物的合成与结构

Synthesis and structure of the mercury chloride complex of 2,2'-(2-bromo-5--butyl-1,3-phenyl-ene)bis-(1-methyl-1-benzimidazole).

作者信息

Rani Varsha, Singh Harkesh B, Butcher Ray J

机构信息

Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India.

Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USA.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 Feb 10;73(Pt 3):341-344. doi: 10.1107/S2056989017001888. eCollection 2017 Mar 1.

DOI:10.1107/S2056989017001888
PMID:28316804
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5347049/
Abstract

In the title mercury complex, -poly[[di-chlorido-mercury(II)]-μ-2,2'-(2-bromo-5--butyl-1,3-phenyl-ene)bis-(1-methyl-1-benzimidazole)-κ:], [HgCl(CHBrN)] , the Hg atom is coordinated by two Cl atoms and by two N atoms from two 2,2'-(2-bromo-5--butyl-1,3-phenyl-ene)bis-(1-methyl-1-benzimidazole) ligands. The metal cation adopts a distorted tetrahedral coordination geometry with with bond angles around mercury of 100.59 (15)° [N-Hg-N] and 126.35 (7)° [Cl-Hg-Cl]. This arrangement gives rise to a zigzag helical 1-D polymer propagating along the axis direction.

摘要

在标题汞配合物 - 聚[[二氯汞（II）]-μ-2,2'-（2-溴-5-丁基-1,3-亚苯基）双-（1-甲基-1-苯并咪唑）-κ:]，[HgCl(CHBrN)] 中，汞原子由两个氯原子以及来自两个2,2'-（2-溴-5-丁基-1,3-亚苯基）双-（1-甲基-1-苯并咪唑）配体的两个氮原子配位。金属阳离子采用扭曲的四面体配位几何构型，汞周围的键角为100.59 (15)° [N-Hg-N] 和126.35 (7)° [Cl-Hg-Cl]。这种排列形成了沿轴方向传播的锯齿形螺旋一维聚合物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47b3/5347049/3e2a65cc9c16/e-73-00341-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47b3/5347049/18302c3104fd/e-73-00341-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47b3/5347049/fa7266cc36cf/e-73-00341-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47b3/5347049/3e2a65cc9c16/e-73-00341-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47b3/5347049/18302c3104fd/e-73-00341-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47b3/5347049/fa7266cc36cf/e-73-00341-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47b3/5347049/3e2a65cc9c16/e-73-00341-fig3.jpg

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