Liu Bitao, Yan Hengqing, Chen Shanyong, Guan Youwei, Wu Guoguo, Jin Rong, Li Lu
Research Institute for New Materials Technology, Chongqing University of Arts and Sciences, Yongchuan, Chongqing, 402160, China.
Chongqing Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Yongchuan, Chongqing, 402160, China.
Nanoscale Res Lett. 2017 Dec;12(1):212. doi: 10.1186/s11671-017-1963-6. Epub 2017 Mar 23.
Silver nanowires without particles are synthesized by a solvothermal method at temperature 150 °C. Silver nanowires are prepared via a reducing agent of glycerol and a capping agent of polyvinylpyrrolidone (M ≈ 1,300,000). Both of them can improve the purity of the as-prepared silver nanowires. With controllable shapes and sizes, silver nanowires are grown continuously up to 10-20 μm in length with 40-50 nm in diameter. To improve the yield of silver nanowires, the different concentrations of AgNO synthesis silver nanowires are discussed. The characterizations of the synthesized silver nanowires are analyzed by UV-visible absorption spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and atomic force microscope (AFM), and silver nanowires are pumped on the cellulose membrane and heated stress on the PET. Then, the cellulose membrane is dissolved by the steam of acetone to prepare flexible transparent conducting thin film, which is detected 89.9 of transmittance and 58 Ω/□. Additionally, there is a close loop connected by the thin film, a blue LED, a pair of batteries, and a number of wires, to determinate directly the film if conductive or not.
无颗粒银纳米线通过溶剂热法在150℃合成。银纳米线通过甘油还原剂和聚乙烯吡咯烷酮(M≈1,300,000)封端剂制备。它们都可以提高所制备银纳米线的纯度。银纳米线形状和尺寸可控,长度连续生长至10 - 20μm,直径为40 - 50nm。为提高银纳米线的产率,讨论了不同浓度的硝酸银合成银纳米线的情况。通过紫外可见吸收光谱、X射线衍射(XRD)、扫描电子显微镜(SEM)和原子力显微镜(AFM)对合成的银纳米线进行表征,并且将银纳米线抽运到纤维素膜上并在PET上施加热应力。然后,用丙酮蒸汽溶解纤维素膜以制备柔性透明导电薄膜,其测得的透过率为89.9%,方阻为58Ω/□。此外,有一个由薄膜、蓝色发光二极管、一对电池和若干电线连接而成的闭合回路,以直接确定薄膜是否导电。