由自由基加成/远程（杂）芳基迁移引发的未活化烯烃的1,2-双官能化型（杂）芳基化反应
1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration.
作者信息
Li Lei, Gu Qiang-Shuai, Wang Na, Song Ping, Li Zhong-Liang, Li Xiao-Hua, Wang Fu-Li, Liu Xin-Yuan
机构信息
Department of Chemistry, South University of Science and Technology of China, Shenzhen, 518055, China.
出版信息
Chem Commun (Camb). 2017 Apr 4;53(28):4038-4041. doi: 10.1039/c6cc09215b.
A novel difunctionalization-type (hetero)arylation of unactivated alkenes has been developed via remote 1,4(5)-(hetero)aryl migration triggered by radical alkene azidation, trifluoromethylation, or phosphonylation. The overall process serves as an unusual and reliable approach for straightforward access to diversely substituted ketones with broad functional group compatibility from readily available substrates and reagents.
通过自由基烯烃叠氮化、三氟甲基化或膦酰化引发的远程1,4（5）-（杂）芳基迁移，开发了一种新型的未活化烯烃双官能化型（杂）芳基化反应。整个过程是一种不同寻常且可靠的方法，可从容易获得的底物和试剂直接获得具有广泛官能团兼容性的各种取代酮。
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