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具有广泛生物活性的1-茚酮的合成。

Synthesis of 1-indanones with a broad range of biological activity.

作者信息

Turek Marika, Szczęsna Dorota, Koprowski Marek, Bałczewski Piotr

机构信息

Institute of Chemistry, Environmental Protection and Biotechnology, The Faculty of Mathematics and Natural Sciences, Jan Długosz University in Częstochowa, Armii Krajowej 13/15, Częstochowa, 42-201, Poland.

Department of Structural Biology, Faculty of Biomedical Sciences and Postgraduate Education, Medical University of Łódź, Żeligowskiego 7/9, 90-752, Łódź, Poland; Department of Heteroorganic Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, Łódź, 90-363, Poland.

出版信息

Beilstein J Org Chem. 2017 Mar 9;13:451-494. doi: 10.3762/bjoc.13.48. eCollection 2017.

DOI:10.3762/bjoc.13.48
PMID:28382183
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5355963/
Abstract

This comprehensive review describes methods for the preparation of 1-indanones published in original and patent literature from 1926 to 2017. More than 100 synthetic methods utilizing carboxylic acids, esters, diesters, acid chlorides, ketones, alkynes, alcohols etc. as starting materials, have been performed. This review also covers the most important studies on the biological activity of 1-indanones and their derivatives which are potent antiviral, anti-inflammatory, analgesic, antimalarial, antibacterial and anticancer compounds. Moreover, they can be used in the treatment of neurodegenerative diseases and as effective insecticides, fungicides and herbicides.

摘要

这篇综述全面描述了1926年至2017年发表在原始文献和专利文献中制备茚满-1-酮的方法。已实施了100多种以羧酸、酯、二酯、酰氯、酮、炔烃、醇等为起始原料的合成方法。本综述还涵盖了关于茚满-1-酮及其衍生物生物活性的最重要研究，这些衍生物是有效的抗病毒、抗炎、止痛、抗疟疾、抗菌和抗癌化合物。此外，它们可用于治疗神经退行性疾病，并可用作有效的杀虫剂、杀菌剂和除草剂。

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ACS Omega. 2025 May 20;10(21):21147-21161. doi: 10.1021/acsomega.4c09705. eCollection 2025 Jun 3.
2
Synthesis of Benzofuran Derivatives via a DMAP-Mediated Tandem Cyclization Reaction Involving -Hydroxy α-Aminosulfones.通过涉及β-羟基α-氨基砜的4-二甲氨基吡啶介导的串联环化反应合成苯并呋喃衍生物。
Molecules. 2024 Aug 6;29(16):3725. doi: 10.3390/molecules29163725.
3
Bismuth(III) triflate: an economical and environmentally friendly catalyst for the Nazarov reaction.

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Mesoporous MnCeOx solid solutions for low temperature and selective oxidation of hydrocarbons.用于烃类低温选择性氧化的介孔锰铈氧化物固溶体
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Indanones as high-potency reversible inhibitors of monoamine oxidase.
三氟甲磺酸铋(III)：一种用于纳扎罗夫反应的经济且环保的催化剂。
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Exploration of bioactive compounds from in Western Ghats of Karnataka using GC-MS.利用气相色谱-质谱联用仪对卡纳塔克邦西高止山脉中的生物活性化合物进行探索。
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Cyclization of 1-aryl-4,4,4-trichlorobut-2-en-1-ones into 3-trichloromethylindan-1-ones in triflic acid.在三氟甲磺酸中将1-芳基-4,4,4-三氯丁-2-烯-1-酮环化生成3-三氯甲基茚满-1-酮
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Palladium-catalyzed addition of acylsilanes across alkynes the activation of a C-Si bond.钯催化酰基硅烷与炔烃的加成反应：C-Si键的活化
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Recent applications of ninhydrin in multicomponent reactions.茚三酮在多组分反应中的最新应用。
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Efficient kinetic resolution in the asymmetric transfer hydrogenation of 3-aryl-indanones: applications to a short synthesis of (+)-indatraline and a formal synthesis of ()-tolterodine.3-芳基茚满酮不对称转移氢化反应中的高效动力学拆分：在（+）-茚达曲林的简短合成及（-）-托特罗定的形式合成中的应用
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茚满酮类作为单胺氧化酶的高效可逆抑制剂。
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Formation of benzo[f]-1-indanone frameworks by regulable intramolecular annulations of gem-dialkylthio trienynes.通过调控偕二烷基硫代三烯炔的分子内环化反应形成苯并[f]-1-茚酮骨架。
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Discovery of indanone derivatives as multi-target-directed ligands against Alzheimer's disease.发现吲酮衍生物作为治疗阿尔茨海默病的多靶点定向配体。
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Enantioselective synthesis of chiral 3-aryl-1-indanones through rhodium-catalyzed asymmetric intramolecular 1,4-addition.通过铑催化的不对称分子内 1,4-加成反应，对映选择性合成手性 3-芳基-1-茚酮。
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