Feng Shangbiao, Li Tao, Du Chenglong, Chen Peng, Song Dengpeng, Li Jinlai, Xie Xingang, She Xuegong
State Key Laboratory of Applied Organic Chemistry, Department of Chemistry, Lanzhou University, Lanzhou, 730000, China.
Chem Commun (Camb). 2017 Apr 20;53(33):4585-4588. doi: 10.1039/c7cc01813d.
A visible-light promoted single electron oxidation of ether enabled by photoredox catalysis has been accomplished. This procedure initiates a novel radical insertion/cyclization cascade reaction to generate phenanthridines and isoquinolines from easily available isocyanides under mild reaction conditions.
通过光氧化还原催化实现了可见光促进的醚的单电子氧化。该过程引发了一种新型的自由基插入/环化级联反应，在温和的反应条件下，由容易获得的异腈生成菲啶和异喹啉。
