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菲及其氮杂类似物的光催化合成。综述。

Photocatalyzed syntheses of phenanthrenes and their aza-analogues. A review.

作者信息

Del Tito Alessandra, Abdulla Havall Othman, Ravelli Davide, Protti Stefano, Fagnoni Maurizio

机构信息

Photogreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, Italy.

Chemistry Department, College of Science, Salahaddin University, Erbil, Iraq.

出版信息

Beilstein J Org Chem. 2020 Jun 25;16:1476-1488. doi: 10.3762/bjoc.16.123. eCollection 2020.

DOI:10.3762/bjoc.16.123
PMID:32647549
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7323630/
Abstract

Phenanthrenes and their aza-analogues have important applications in materials science and in medicine. Aim of this review is to collect recent reports describing their synthesis, which make use of radical cyclizations promoted by a visible light-triggered photocatalytic process.

摘要

菲及其氮杂类似物在材料科学和医学领域有着重要应用。本综述的目的是收集近期描述其合成方法的报告，这些合成方法利用了可见光触发的光催化过程促进的自由基环化反应。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/007ff0f5c81c/Beilstein_J_Org_Chem-16-1476-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/630c7c553cc5/Beilstein_J_Org_Chem-16-1476-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/bbda4f5eda0b/Beilstein_J_Org_Chem-16-1476-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/ab5ab1c44304/Beilstein_J_Org_Chem-16-1476-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/007ff0f5c81c/Beilstein_J_Org_Chem-16-1476-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/630c7c553cc5/Beilstein_J_Org_Chem-16-1476-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/bbda4f5eda0b/Beilstein_J_Org_Chem-16-1476-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/ab5ab1c44304/Beilstein_J_Org_Chem-16-1476-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/98b1/7323630/007ff0f5c81c/Beilstein_J_Org_Chem-16-1476-g006.jpg

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Angew Chem Int Ed Engl. 2020 Jun 8;59(24):9324-9329. doi: 10.1002/anie.202000892. Epub 2020 Apr 2.
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Expeditious synthesis of phenanthridines through a Pd/MnO-mediated C-H arylation/oxidative annulation cascade from aldehydes, aryl iodides and amino acids.通过 Pd/MnO 介导的 C-H 芳基化/氧化环化级联反应，从醛、芳基碘化物和氨基酸快速合成菲啶。
Chem Commun (Camb). 2020 Mar 3;56(18):2775-2778. doi: 10.1039/d0cc00300j.
3
Annulation of Benzamides with Arynes Using Palladium with Photoredox Dual Catalysis.
钯与光氧化还原双催化作用下苯甲酰胺与芳炔的环化反应
J Org Chem. 2019 Jul 19;84(14):9007-9016. doi: 10.1021/acs.joc.9b00893. Epub 2019 Jul 2.
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Visible-light-induced radical trifluoromethylthiolation of N-(o-cyanobiaryl)acrylamides.可见光诱导的 N-(邻氰基二芳基)丙烯酰胺的自由基三氟甲基化反应。
Org Biomol Chem. 2019 Mar 27;17(13):3374-3380. doi: 10.1039/c9ob00342h.
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