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蜕皮材料:通过蛇皮般的剥落实现严重损伤后的超疏水恢复。

Molting Materials: Restoring Superhydrophobicity after Severe Damage via Snakeskin-like Shedding.

机构信息

Department of Microsystems Engineering, University of Freiburg , Georges-Köhler-Allee 103, 79110 Freiburg, Germany.

出版信息

Langmuir. 2017 May 16;33(19):4833-4839. doi: 10.1021/acs.langmuir.7b00814. Epub 2017 May 1.

DOI:10.1021/acs.langmuir.7b00814
PMID:28409938
Abstract

The nanostructures that are required to generate superhydrophobic surfaces are always sensitive to shear and are easily damaged, especially by scratching with sharp objects. As a result of this destruction, the water repellency will be lost. We introduce a novel approach to restoring the original surface properties after mechanical damage. In this approach, the damaged layer is shed like the skin of a snake. This is demonstrated with a three-layer stack as a proof-of-principle system: when the original, superhydrophobic surface layer is damaged, this leads to the dissolution of a sacrificial layer below it. Thus, the damaged layer is shed, a new unscathed surface is uncovered, and superhydrophobicity can easily be restored after a short washing.

摘要

生成超疏水表面所需的纳米结构对剪切总是很敏感,很容易损坏,尤其是被尖锐物体划伤。由于这种破坏,疏水性将会丧失。我们提出了一种在机械损伤后恢复原始表面性能的新方法。在这种方法中,损坏的层像蛇皮一样剥落。我们使用一个三层堆叠作为原理验证系统来证明这一点:当原始的超疏水表面层被损坏时,这会导致下面的牺牲层溶解。因此,损坏的层剥落,一个新的未受损的表面暴露出来,并且在短时间的清洗后,很容易恢复超疏水性。

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