有机六聚体笼状家族中的一种手性成员。
A chiral member of the family of organic hexameric cages.
作者信息
Wierzbicki M, Głowacka A A, Szymański M P, Szumna A
机构信息
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-22 Warsaw, Poland.
出版信息
Chem Commun (Camb). 2017 May 4;53(37):5200-5203. doi: 10.1039/c7cc02245j.
PMID:28443869
Abstract
A cubic nanocage (O symmetry) that exhibits inherent chirality and has a covalent, rigid skeleton with molecule-sized entrance portals was obtained by means of dynamic covalent chemistry using a reaction between aldehyde-functionalized resorcin[4]arene and hydrazine.
摘要
通过醛基功能化间苯二酚[4]芳烃与肼之间的反应，利用动态共价化学方法获得了一种具有固有手性的立方纳米笼（O 对称性），它具有共价刚性骨架和分子大小的入口通道。
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