难以捉摸的五氯化氮杂富勒烯C NCl的合成、结构表征及晶体堆积
Synthesis, Structural Characterization, and Crystal Packing of the Elusive Pentachlorinated Azafullerene C NCl.
作者信息
Amsharov Konstantin Yu, Holzwarth Johannes, Roshchyna Kateryna, Sharapa Dmitry I, Hampel Frank, Hirsch Andreas
机构信息
Lehrstuhl für Organische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestrasse 42, 91054, Erlangen, Germany.
Computer-Chemie-Centrum, Friedrich-Alexander-Universität Erlangen-Nürnberg, Nägelsbachstrasse 25, 91052, Erlangen, Germany.
出版信息
Chemistry. 2017 Jul 6;23(38):9014-9017. doi: 10.1002/chem.201700802. Epub 2017 May 2.
We report on the synthesis and the structure elucidation of the elusive azafullerene pentachloride C NCl , which was obtained by high temperature halogenation of (C N) . The exceptionally strong host-guest interaction of the title compound in the solid is discussed.
我们报道了难以捉摸的五氯化氮杂富勒烯C₅NCl₅的合成及结构解析，它是通过（C₅N）的高温卤化反应得到的。本文还讨论了该标题化合物在固态时异常强烈的主客体相互作用。
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