Stable (sila)difluoromethylboranes via C-F activation of fluoroform derivatives.
作者信息
Ito Shigekazu, Kato Naoto, Mikami Koichi
机构信息
Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8552, Japan.
出版信息
Chem Commun (Camb). 2017 May 17;53(40):5546-5548. doi: 10.1039/c7cc02327h.
PMID:28470296
Abstract
Lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-uide activates the C-F linkage of fluoroform (CFH) and the Ruppert-Prakash reagent (CFSiMe) to provide difluoromethyl-substituted boranes as air-stable compounds.
摘要
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