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F 气体的再利用:氟化学面临的挑战和机遇。

Repurposing of F-gases: challenges and opportunities in fluorine chemistry.

机构信息

Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, 82 Wood Lane, Shepherds Bush, London, W12 0BZ, UK.

出版信息

Chem Soc Rev. 2022 Jun 20;51(12):4977-4995. doi: 10.1039/d1cs01072g.

Abstract

Fluorinated gases (F-gases) are routinely employed as refrigerants, blowing agents, and electrical insulators. These volatile compounds are potent greenhouse gases and consequently their release to the environment creates a significant contribution to global warming. This review article seeks to summarise: (i) the current applications of F-gases, (ii) the environmental issues caused by F-gases, (iii) current methods of destruction of F-gases and (iv) recent work in the field towards the chemical repurposing of F-gases. There is a great opportunity to tackle the environmental and sustainability issues created by F-gases by developing reactions that repurpose these molecules.

摘要

含氟气体(F-gases)通常被用作制冷剂、发泡剂和电绝缘体。这些挥发性化合物是强效温室气体,因此它们向环境中的释放对全球变暖造成了重大贡献。本文旨在综述:(i)F-gases 的当前应用,(ii)F-gases 引起的环境问题,(iii)F-gases 的当前销毁方法,以及(iv)在化学重新利用 F-gases 领域的最新工作。通过开发重新利用这些分子的反应,为解决 F-gases 带来的环境和可持续性问题提供了绝佳的机会。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a7a1/9207706/8ce311b2b4e2/d1cs01072g-f1.jpg

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