Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, 82 Wood Lane, Shepherds Bush, London, W12 0BZ, UK.
Chem Soc Rev. 2022 Jun 20;51(12):4977-4995. doi: 10.1039/d1cs01072g.
Fluorinated gases (F-gases) are routinely employed as refrigerants, blowing agents, and electrical insulators. These volatile compounds are potent greenhouse gases and consequently their release to the environment creates a significant contribution to global warming. This review article seeks to summarise: (i) the current applications of F-gases, (ii) the environmental issues caused by F-gases, (iii) current methods of destruction of F-gases and (iv) recent work in the field towards the chemical repurposing of F-gases. There is a great opportunity to tackle the environmental and sustainability issues created by F-gases by developing reactions that repurpose these molecules.
含氟气体(F-gases)通常被用作制冷剂、发泡剂和电绝缘体。这些挥发性化合物是强效温室气体,因此它们向环境中的释放对全球变暖造成了重大贡献。本文旨在综述:(i)F-gases 的当前应用,(ii)F-gases 引起的环境问题,(iii)F-gases 的当前销毁方法,以及(iv)在化学重新利用 F-gases 领域的最新工作。通过开发重新利用这些分子的反应,为解决 F-gases 带来的环境和可持续性问题提供了绝佳的机会。