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用于从废水中去除染料的纳米材料概述。

An overview of nanomaterials applied for removing dyes from wastewater.

作者信息

Cai Zhengqing, Sun Youmin, Liu Wen, Pan Fei, Sun Peizhe, Fu Jie

机构信息

Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433, China.

School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA, 30332, USA.

出版信息

Environ Sci Pollut Res Int. 2017 Jul;24(19):15882-15904. doi: 10.1007/s11356-017-9003-8. Epub 2017 May 5.

Abstract

Organic dyes are one of the most commonly discharged pollutants in wastewaters; however, many conventional treatment methods cannot treat them effectively. Over the past few decades, we have witnessed rapid development of nanotechnologies, which offered new opportunities for developing innovative methods to treat dye-contaminated wastewater with low price and high efficiency. The large surface area, modified surface properties, unique electron conduction properties, etc. offer nanomaterials with excellent performances in dye-contaminated wastewater treatment. For examples, the agar-modified monometallic/bimetallic nanoparticles have the maximum methylene blue adsorption capacity of 875.0 mg/g, which are several times higher than conventional adsorbents. Among various nanomaterials, the carbonaceous nanomaterials, nano-sized TiO, and graphitic carbon nitride (g-CN) are considered as the most promising nanomaterials for removing dyes from water phase. However, some challenges, such as high cost and poor separation performance, still limit their engineering application. This article reviewed the recent advances in the nanomaterials used for dye removal via adsorption, photocatalytic degradation, and biological treatment. The modification methods for improving the effectiveness of nanomaterials are highlighted. Finally, the current knowledge gaps of developing nanomaterials on the environmental application were discussed, and the possible further research direction is proposed.

摘要

有机染料是废水中最常见的排放污染物之一;然而,许多传统处理方法无法有效处理它们。在过去几十年里,我们见证了纳米技术的快速发展,这为开发低成本、高效率处理染料污染废水的创新方法提供了新机遇。大表面积、改性表面性质、独特的电子传导性质等赋予了纳米材料在处理染料污染废水方面的优异性能。例如,琼脂改性的单金属/双金属纳米粒子对亚甲基蓝的最大吸附容量为875.0 mg/g,比传统吸附剂高出数倍。在各种纳米材料中,碳质纳米材料、纳米TiO和石墨相氮化碳(g-CN)被认为是从水相中去除染料最有前景的纳米材料。然而,一些挑战,如成本高和分离性能差,仍然限制了它们的工程应用。本文综述了用于通过吸附、光催化降解和生物处理去除染料的纳米材料的最新进展。重点介绍了提高纳米材料有效性的改性方法。最后,讨论了开发纳米材料在环境应用方面当前的知识空白,并提出了可能的进一步研究方向。

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