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基于热激活延迟荧光主体的多色发光电化学电池。

Multi-Colored Light-Emitting Electrochemical Cells Based on Thermal Activated Delayed Fluorescence Host.

机构信息

Department of Materials Science and Engineering, University of California, Los Angeles, California, 90095, USA.

出版信息

Sci Rep. 2017 May 8;7(1):1524. doi: 10.1038/s41598-017-01812-2.

Abstract

Light-emitting electrochemical cells (LECs) with the thermally activated delayed fluorescence(TADF) host and phosphorescent guests were fabricated using solution process. It is demonstrated for the first time that TADF, a well-known phenomenon that helps to increase electroluminescence efficiency by harvesting excitons from triplet states, is used as a host in LECs. Devices with green, yellow, red and warm white emissions were fabricated, with the best devices showing more than 7000 cd/m stable emission and a peak efficiency over 7 cd/A. Under high voltage stress, a burst of extremely high luminance of over 30,000 cd/m was observed. All these LEC devices are extremely simple with only one active layer. Thus, our results could pave way to produce low- cost light source with high luminance, using TADF molecules.

摘要

采用溶液法制备了热致延迟荧光(TADF)主体和磷光客体的发光电化学电池(LECs)。首次证明,TADF 是一种众所周知的现象,可通过从三重态中收集激子来提高电致发光效率,可将其用作 LEC 的主体。制备了绿光、黄光、红光和暖白光发射器件,其中最佳器件的稳定发射亮度超过 7000 cd/m,峰值效率超过 7 cd/A。在高电压应力下,观察到超过 30000 cd/m 的极高亮度的突发。所有这些 LEC 器件都非常简单,只有一个有源层。因此,我们的结果可能为使用 TADF 分子生产低成本、高光亮度的光源铺平道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f757/5431554/70ec27108ec8/41598_2017_1812_Fig1_HTML.jpg

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