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关于人工湿地在去除最近发布的欧盟法规中列出的优先物质和新关注污染物方面的应用的综述。

A review on the application of constructed wetlands for the removal of priority substances and contaminants of emerging concern listed in recently launched EU legislation.

机构信息

Laboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials (LSRE-LCM), Faculdade de Engenharia, Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal.

Interdisciplinary Centre of Marine and Environmental Research (CIIMAR/CIMAR), Universidade do Porto, Terminal de Cruzeiros do Porto de Leixões, Av. General Norton de Matos s/n, 4450-208 Matosinhos, Portugal.

出版信息

Environ Pollut. 2017 Aug;227:428-443. doi: 10.1016/j.envpol.2017.04.060. Epub 2017 May 6.

Abstract

The presence of organic pollutants in the aquatic environment, usually found at trace concentrations (i.e., between ng L and μg L or even lower, known as micropollutants), has been highlighted in recent decades as a worldwide environmental concern due to their difficult elimination by conventional water and wastewater treatment processes. The relevant information on constructed wetlands (CWs) and their application for the removal of a specific group of pollutants, 41 organic priority substances/classes of substances (PSs) and 8 certain other substances with environmental quality standards (EQS) listed in Directive 2013/39/EU as well as 17 contaminants of emerging concern (CECs) of the Watch List of Decision 2015/495/EU, is herein reviewed. Studies were found for 24 PSs and 2 other substances with EQS: octylphenol, nonylphenol, perfluorooctane sulfonic acid, di(2-ethylhexyl)phthalate, trichloromethane, dichloromethane, 1,2-dichloroethane, pentachlorobenzene, benzene, polychlorinated dibenzo-p-dioxins, naphthalene, fluoranthene, trifluralin, alachlor, isoproturon, diuron, tributyltin compounds, simazine, atrazine, chlorpyrifos (chlorpyrifos-ethyl), chlorfenvinphos, hexachlorobenzene, pentachlorophenol, endosulfan, dichlorodiphenyltrichloroethane (or DDT) and dieldrin. A few reports were also published for 8 CECs: imidacloprid, erythromycin, clarithromycin, azithromycin, diclofenac, estrone, 17-beta-estradiol and 17-alpha-ethinylestradiol. No references were found for the other 17 PSs, 6 certain other substances with EQS and 9 CECs listed in EU legislation.

摘要

近几十年来,由于常规水和废水处理工艺难以去除痕量浓度(即 ng/L 至 μg/L 甚至更低,称为微量污染物)的有机污染物,因此水生环境中的有机污染物已成为全球关注的环境问题。本文综述了有关人工湿地 (CW) 的相关信息及其在去除特定污染物组方面的应用,这些污染物包括指令 2013/39/EU 中列出的 41 种优先有机物质/物质类别 (PSs) 和 8 种具有环境质量标准 (EQS) 的其他特定物质,以及指令 2015/495/EU 的关注物质清单中列出的 17 种新兴关注污染物 (CECs)。研究了 24 种 PSs 和 2 种具有 EQS 的其他物质:辛基酚、壬基酚、全氟辛烷磺酸、邻苯二甲酸二(2-乙基己基)酯、三氯甲烷、二氯甲烷、1,2-二氯乙烷、五氯苯、苯、多氯代二苯并对二恶英、萘、荧蒽、氟乐灵、甲草胺、异丙隆、西玛津、莠去津、三丁基锡化合物、莠去津、莠去津、氯吡硫磷(氯吡硫磷-乙基)、氯芬威、六氯苯、五氯苯酚、硫丹、滴滴涕和狄氏剂。也有少数报道涉及 8 种 CECs:吡虫啉、红霉素、克拉霉素、阿奇霉素、双氯芬酸、雌酮、17-β-雌二醇和 17-α-乙炔基雌二醇。对于其他 17 种 PSs、6 种其他具有 EQS 的物质和欧盟法规中列出的 9 种 CECs,没有找到相关参考文献。

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