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通过静电纺丝纳米纤维增强基于量子点的白光发光二极管的光转换复合材料的散热性能。

Enhancing the thermal dissipation of a light-converting composite for quantum dot-based white light-emitting diodes through electrospinning nanofibers.

机构信息

Hubei Key Laboratory of Waterjet Theory and New Technology, School of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, People's Republic of China. The Institute of Technological Sciences, Wuhan University, Wuhan 430072, People's Republic of China.

出版信息

Nanotechnology. 2017 Jun 30;28(26):265204. doi: 10.1088/1361-6528/aa72d6. Epub 2017 May 12.

Abstract

Quantum dots (QDs) have been developed as one of the most promising light-converting materials for white light-emitting diodes (LEDs). In current QD-based LED packaging structures, composites of QDs and polymers are used as light-converting layers. However, the ultralow thermal conductivity of such composites seriously hinders the dissipation of QD-generating heat. In this paper, we demonstrate a method to enhance the thermal dissipation of QD-polymer composites through electrospinning polymer nanofibers. QD-polymer films embedded by electrospun nanofibers were prepared. Benefitting from aligned polymer chains in the electrospun nanofibers, the through-panel and in-panel thermal conductivities of the proposed QD-polymer film increased by 39.9% and 423.1%, respectively, compared to traditional QD-polymer film. The proposed and traditional QD-polymer films were both packaged on chip on board (CoB) LEDs for experimental comparison. Compared to traditional QD-polymer film, the luminous flux and luminous efficiency of the LEDs were increased by up to 51.8% and 42.9% by the proposed QD-polymer film under a current of 800 mA, respectively. With an increase in the driving current from 20-800 mA, the correlated color temperature (CCT) variation decreased by 72.7%. The maximum temperatures in the QD-polymer films were reduced from 419 K-411 K under a driving current of 200 mA.

摘要

量子点 (QDs) 已被开发为最有前途的用于白光发光二极管 (LED) 的光转换材料之一。在当前基于 QD 的 LED 封装结构中,将 QD 和聚合物的复合材料用作光转换层。然而,这种复合材料的超低导热系数严重阻碍了 QD 产生的热量的耗散。在本文中,我们展示了一种通过静电纺丝聚合物纳米纤维来增强 QD-聚合物复合材料散热的方法。制备了嵌入电纺纳米纤维的 QD-聚合物薄膜。由于电纺纳米纤维中聚合物链的取向,与传统的 QD-聚合物薄膜相比,所提出的 QD-聚合物薄膜的面内热导率和面内热导率分别提高了 39.9%和 423.1%。所提出的和传统的 QD-聚合物薄膜都被封装在板上芯片 (CoB) LED 上进行实验比较。与传统的 QD-聚合物薄膜相比,在 800 mA 的电流下,所提出的 QD-聚合物薄膜使 LED 的光通量和光效分别提高了 51.8%和 42.9%。随着驱动电流从 20-800 mA 的增加,相关色温 (CCT) 的变化降低了 72.7%。在 200 mA 的驱动电流下,QD-聚合物薄膜中的最高温度从 419 K 降低到 411 K。

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