使用硅烷和烯丙基氯进行铜催化的丙二烯氢烯基化反应。
Copper-catalyzed hydroallylation of allenes employing hydrosilanes and allyl chlorides.
作者信息
Fujihara Tetsuaki, Yokota Ken, Terao Jun, Tsuji Yasushi
机构信息
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.
出版信息
Chem Commun (Camb). 2017 Jul 11;53(56):7898-7900. doi: 10.1039/c7cc02816d.
PMID:28513657
Abstract
The hydroallylation of allenes was developed by employing a hydrosilane and allyl chlorides in the presence of a copper catalyst. The reaction provided (E)-1,5-dienes mainly in good to high yields.
摘要
通过在铜催化剂存在下使用硅烷和烯丙基氯，实现了丙二烯的氢烯基化反应。该反应主要以良好至高收率提供（E）-1,5-二烯。
Zotero 插件