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用于有机场效应晶体管(OFET)的基于高性能溶液可加工四硫代并四苯(TTAR)的小分子。

High performance solution-processable tetrathienoacene (TTAR) based small molecules for organic field effect transistors (OFETs).

作者信息

Vegiraju Sureshraju, Huang Deng-Yi, Priyanka Pragya, Li Yo-Shan, Luo Xian-Lun, Hong Shao-Huan, Ni Jen-Shyang, Tung Shih-Huang, Wang Chien-Lung, Lien Wei-Chieh, Yau Shueh Lin, Liu Cheng-Liang, Chen Ming-Chou

机构信息

Department of Chemistry, National Central University, Taoyuan, 32001, Taiwan.

出版信息

Chem Commun (Camb). 2017 May 30;53(43):5898-5901. doi: 10.1039/c7cc02714a.

Abstract

Three new organic semiconductors with alkyl chain-substituted tetrathienoacene (TTAR) as the central core and both ends capped with thiophene (DT-TTAR), thienothiophene (DTT-TTAR) and dithienothiophene (DDTT-TTAR) have been synthesized and characterized for organic field effect transistor (OFET) applications. A hole mobility of 0.81 cm V s was achieved for the DDTT-TTAR film, which represents the highest mobility yet found for a solution-processable p-type TTAR-based small molecular semiconductors.

摘要

合成了三种以烷基链取代的四硫并并四苯(TTAR)为中心核且两端分别被噻吩(DT-TTAR)、噻吩并噻吩(DTT-TTAR)和二噻吩并噻吩(DDTT-TTAR)封端的新型有机半导体,并对其进行了表征,以用于有机场效应晶体管(OFET)应用。DDTT-TTAR薄膜实现了0.81 cm² V⁻¹ s⁻¹的空穴迁移率,这代表了可溶液加工的基于p型TTAR的小分子半导体迄今发现的最高迁移率。

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