Larkin Andrew, Geddes Jeffrey A, Martin Randall V, Xiao Qingyang, Liu Yang, Marshall Julian D, Brauer Michael, Hystad Perry
College of Public Health and Human Sciences, Oregon State University , Milam 20A, Corvallis, Oregon 97331, United States.
Department of Earth and Environment, Boston University , Boston, Massachusetts 02215, United States.
Environ Sci Technol. 2017 Jun 20;51(12):6957-6964. doi: 10.1021/acs.est.7b01148. Epub 2017 Jun 5.
Nitrogen dioxide is a common air pollutant with growing evidence of health impacts independent of other common pollutants such as ozone and particulate matter. However, the worldwide distribution of NO exposure and associated impacts on health is still largely uncertain. To advance global exposure estimates we created a global nitrogen dioxide (NO) land use regression model for 2011 using annual measurements from 5,220 air monitors in 58 countries. The model captured 54% of global NO variation, with a mean absolute error of 3.7 ppb. Regional performance varied from R = 0.42 (Africa) to 0.67 (South America). Repeated 10% cross-validation using bootstrap sampling (n = 10,000) demonstrated a robust performance with respect to air monitor sampling in North America, Europe, and Asia (adjusted R within 2%) but not for Africa and Oceania (adjusted R within 11%) where NO monitoring data are sparse. The final model included 10 variables that captured both between and within-city spatial gradients in NO concentrations. Variable contributions differed between continental regions, but major roads within 100 m and satellite-derived NO were consistently the strongest predictors. The resulting model can be used for global risk assessments and health studies, particularly in countries without existing NO monitoring data or models.
二氧化氮是一种常见的空气污染物,越来越多的证据表明其对健康有影响,且独立于臭氧和颗粒物等其他常见污染物。然而,全球范围内二氧化氮暴露的分布情况以及对健康的相关影响仍很大程度上不确定。为了改进全球暴露估计,我们利用58个国家5220个空气监测站的年度测量数据,创建了一个2011年全球二氧化氮(NO)土地利用回归模型。该模型捕捉了全球54%的二氧化氮变化,平均绝对误差为3.7 ppb。区域表现从R = 0.42(非洲)到0.67(南美洲)不等。使用自助抽样(n = 10,000)进行的重复10%交叉验证表明,在北美、欧洲和亚洲,该模型在空气监测站抽样方面表现稳健(调整后的R在2%以内),但在非洲和大洋洲(调整后的R在11%以内)表现不佳,因为那里的二氧化氮监测数据稀少。最终模型包括10个变量,这些变量捕捉了城市间和城市内二氧化氮浓度的空间梯度。不同大陆区域的变量贡献有所不同,但100米内的主要道路和卫星衍生的二氧化氮一直是最强的预测因子。所得模型可用于全球风险评估和健康研究,特别是在没有现有二氧化氮监测数据或模型的国家。