Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
Department of Inorganic Chemistry, University of Chemistry and Technology Prague, Technicka 5, 166 28 Prague 6, Czech Republic.
Chem Soc Rev. 2017 Jul 31;46(15):4450-4463. doi: 10.1039/c7cs00215g.
Stoichiometric derivatives of graphene, having well-defined chemical structure and well-defined chemical bonds, are of a great interest to the 2D materials research. Hydrogenated graphene (graphene), fluorographene, hydroxygraphene (graphol), thiographene, cyanographene, aminographene, graphene acid pose unique and well defined chemical and physical properties, allowing their further transformation and application in the devices. Here we overview various methods of their synthesis and discuss their chemistry and properties. It is expected that the family of stochiometric derivatives of graphene will grow beyond listed examples in the near future.
具有明确化学结构和化学键的石墨烯化学计量衍生物是 2D 材料研究的重要关注点。氢化石墨烯（石墨烯）、氟化石墨烯、羟基化石墨烯（Graphol）、噻吩化石墨烯、氰基化石墨烯、氨基化石墨烯、石墨烯酸具有独特且明确的化学和物理性质，允许对其进行进一步转化并应用于器件中。在此，我们综述了它们的各种合成方法，并讨论了它们的化学性质和性能。预计在不久的将来，石墨烯化学计量衍生物的家族将超出列出的例子。
